Process for producing 3-pentenoic esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C 6736

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active

043329667

ABSTRACT:
A process is disclosed for producing a 3-pentenoic ester which comprises reacting butadiene, carbon monoxide and an alcohol in the presence of cobalt carbonyl catalyst, characterized in that the reaction is carried out in a reaction medium composed of at least two solvents selected from the group consisting of pyridine, quinoline, isoquinoline and substituted pyridine, substituted quinoline and substituted isoquinoline in which substituent or substituents are selected from the group consisting of alkyl having 1-6 carbon atoms, alkenyl having 1-6 carbon atoms, aryl, alkylaryl having 7-10 carbon atoms and aralkyl having 7-10 carbon atoms.

REFERENCES:
patent: 2882299 (1959-04-01), Smolin et al.
patent: 3778466 (1973-12-01), Matsuda
Matsuda, A. "The Cobalt Carbonyl-catalyzed Hydroesterification of Butadiene with Carbon Monoxide and Methanol", Bulletin of the Chemical Society of Japan, vol. 46, 524-530 (1973).

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