Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1991-12-17
1993-06-08
Ivy, C. Warren
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
C07D31120
Patent
active
052181294
ABSTRACT:
A process for producing 3,4-dihydrocoumarin comprising cyclization and dehydrogenation of a 3-(2-cyclohexanoyl)propionic acid ester, in which a reaction mixture obtained by the cyclization and dehydrogenation is washed with an alkali to reduce the dihydrocinnamic acid content of the reaction mixture to 1% by weight or less and/or previously distilling the reaction mixture to remove high-boiling substances, and then subjected to rectification to recover 3,4-dihydrocoumarin. The thus obtained 3,4-dihydrocoumarin has high purity and high quality sufficient for use as a perfume as it is.
REFERENCES:
patent: 3442910 (1989-05-01), Thweatt
Chemical Abstracts, vol. 115, No. 17, Oct. 28, 1991, p. 905, 183103w and 183104x.
Nishida Yoshitaka
Okusako Kensen
Sakai Kiyomi
Shirafuji Tamio
Ivy C. Warren
Sumitomo Chemical Co,. Ltd.
Trinh Ba K.
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