Process for producing 2-chloropyridine

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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B01J 110

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active

039692051

ABSTRACT:
Pyridine is reacted with chlorine in the presence of water by photolytic reaction under irradiation of photolytic light, using halogenated hydrocarbon such as carbon tetrachloride as a diluent. When the amount of water added exceeds at least 0.01 moles per one mole of pyridine, an effect of water addition appears, but usually addition of 0.2 to 10 moles, preferably 0.5 to 5 moles of water per one mole of pyridine makes the reaction proceed smoothly without any trouble, and ensures increase in yield and selectivity of 2-chloropyridine. The present process can be carried out in either gaseous or liquid phase.

REFERENCES:
patent: 3297556 (1967-01-01), Boudakian et al.

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