Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...
Patent
1993-01-21
1994-06-14
Pal, Asok
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By ring formation from nonring moiety, e.g., aromatization,...
585407, 585419, 585420, C07C 500
Patent
active
053211782
ABSTRACT:
A process for efficiently producing 2,6-dimethylnaphthalene which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as the starting raw material to a cyclization dehydrogenation reaction in the presence of a catalyst comprising (a) a palladium component, (b) an alkali or alkaline earth metal compound and (c) aluminum oxide. The process enables the production of highly pure 2,6-dimethylnaphthalene in a high yield at a low cost. The catalyst used in the process affords high safety and stability.
REFERENCES:
patent: 3931348 (1976-01-01), Taniguchi et al.
patent: 4650565 (1987-03-01), Jacobson et al.
patent: 5068480 (1991-11-01), Takagawa et al.
patent: 5185484 (1993-02-01), Del Rossi et al.
Fushimi Norio
Inamasa Kenji
Takagawa Makoto
Achutamurthy P.
Mitsubishi Gas Chemical Company Inc.
Pal Asok
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