Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing
Patent
1983-07-06
1985-08-13
Warren, Charles F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Halogen containing
570220, 570257, 570228, 570229, 570253, C07C 1700
Patent
active
045351945
ABSTRACT:
A process is disclosed for preparing 1,1,2,3-tetrachloropropene comprising allylic rearrangement of 2,3,3,3-tetrachloropropene using a substantially anhydrous ferric chloride catalyst. Alternatively, 1,1,2,3-tetrachloropropene is prepared by dehydrochlorination of 1,1,1,2,3-pentachloropropane using a ferric chloride catalyst. Process schemes commencing with the preparation of the precursor 1,1,1,3-tetrachloropropane by reaction of ethylene with carbon tetrachloride are also disclosed.
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Boska Joseph A.
Keane J. Timothy
Monsanto Co.
Shear Richard H.
Warren Charles F.
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