Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1991-05-06
1993-02-23
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560 97, 560193, 560204, C07C 6738
Patent
active
051891980
ABSTRACT:
A process for efficiently preparing an unsaturated dicarboxylic acid diester, which comprises reacting a conjugated diene, carbon monoxide, an alcohol and oxygen in the presence of a catalyst comprising (a) a platinum metal, a salt thereof or a complex compound of a platinum metal, (b) at least one metal salt selected from the group consisting of a copper salt, an iron salt and a manganese salt and (C) at least one compound selected from the group consisting of (1) an alkali metal compound or an alkaline earth metal compound, (2) a rare earth metal compound, (3) a metal compound of the groups IIIA, IVA, IVB, VA, VB or VIA, and (4) a metal carbonyl complex. The unsaturated dicarboxylic acid diester is useful as an intermediate material in industrial chemical processes and can be efficiently prepared without the use of a dehydrating agent.
REFERENCES:
patent: 3819669 (1974-06-01), Knifton
patent: 3892788 (1975-07-01), Knifton
patent: 3919272 (1975-11-01), Knifton
Patent Abstracts of Japan, C Section, vol. 11, No. 136, Apr. 30, 1987-61-275246.
Patent Abstracts of Japan, C Section, vol. 6, No. 122, Jul. 7, 1982-57-48942.
Ishibashi Tetsuo
Kanzawa Mitsugu
Kumazawa Takashi
Clarke Vera C.
Dees Jos,e G.
Idemitsu Petrochemical Co. Ltd.
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