Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1978-05-01
1980-08-26
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 4930
Patent
active
042195055
ABSTRACT:
2,2,6,6-Tetrachloro(or tetrabromo)cyclohexanone is prepared by reacting in the liquid phase chlorine or bromine with a cyclohexanone compound of formula ##STR1## where Y is hydrogen or chlorine (to produce the tetrachloro compound) or hydrogen or bromine (to produce the tetrabromo compound) in the presence as catalyst of an organophosphorus compound of formula ##STR2## where Z is chlorine or bromine; n is 0 or 1; and when n is 0, m is 0 or 2, R.sup.1 is alkyl or phenyl, and R.sup.2 and R.sup.3 are hydrogen, alkyl or phenyl; and when n is 1, m is 0, and R.sup.1, R.sup.2 and R.sup.3 are the same and each is ##STR3## alkyl or phenyl, or R.sup.1 is hydrogen and R.sup.2 and R.sup.3 are alkyl or phenyl;
REFERENCES:
patent: 3894087 (1975-07-01), Gilbert et al.
patent: 3927106 (1975-12-01), Gilbert et al.
patent: 3988369 (1976-10-01), Pearson
Miller John
Needham Brian J.
Fisons Limited
Lone Werren B.
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