Process for preparing tertiary phosphines

Details Process for preparing tertiary phosphines Process for preparing tertiary phosphines

1983-11-25

1985-04-30

Sneed, Helen M. S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus containing

568 8, C07F 950

Patent

active

045145750

ABSTRACT:
Tertiary phosphine oxides, such as triphenylphosphine oxide, are reduced to the corresponding phosphines with trichlorosilane in an inert halogenated hydrocarbon solvent.

REFERENCES:
patent: 3261871 (1966-07-01), Fritzsche
patent: 3405180 (1968-10-01), Natoli
patent: 3780111 (1973-12-01), Young et al.
patent: 4131624 (1978-12-01), Davis et al.
Chemical Abstracts, 62, 10457d, (1965).
Tetrahedron Letters, No. 17, pp. 1157-1162, (1965).
Kosolopoff, Organo Phosphorus Compounds, Wiley-Intersc., N.Y., VI, pp. 45-47, (1972).

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