Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1978-10-17
1980-04-08
Siegel, Alan
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5142
Patent
active
041974123
ABSTRACT:
A process for the continuous preparation of pure terephthalic acid by oxidation of p-xylene with molecular oxygen in acetic acid solvent comprising conducting the oxidation at a temperature of 205.degree. to 230.degree. C. in the presence of an oxidation catalyst comprising (a) a cobalt compound in an amount of at least 120 ppm and less than 200 ppm as cobalt based on the weight of solvent, (b) a manganese compound sufficient to provide a manganese to cobalt weight ratio of 0.5 to 1.5 and (c) a bromine compound selected from hydrogen bromide, cobalt bromide and manganese bromide in an amount of 200 to 1,000 ppm as bromine based on the weight of solvent, while the water content of the liquid phase of the reaction system is kept at 4 to 14 percent by weight.
REFERENCES:
patent: 3970696 (1976-07-01), Shigeyasu et al.
Hashizume Hiroshi
Izumisawa Yoshiaki
Kimura Tsuneo
Mitsubishi Chemical Industries Limited
Siegel Alan
LandOfFree
Process for preparing terephthalic acid does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for preparing terephthalic acid, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing terephthalic acid will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-974575