Process for preparing spherical and porous vinyl resin particles

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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521 56, 521 65, 526202, 5263442, 5263443, C08F 220

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active

043606512

ABSTRACT:
Process for making porous, substantially spherical particles of vinyl polymers or resins by the use of the suspension polymerization technique. In the polymerization there is employed a water-insoluble dispersant comprised of a substantially unneutralized crosslinked interpolymer of one or more carboxylic acid monomers with a polyunsaturated compound having a plurality of terminally unsaturated polymerizable groups and optionally a water-soluble surfactant with a polyether type hydrophilic segment using rapid stirring or high agitation while employing a monomer-soluble free radical yielding polymerization catalyst. When using the new process, the polymer buildup in the reactor is substantially reduced.

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