Process for preparing sec-butyl alcohol and sec-butyl tert-butyl

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568918, C07C 4106, C07C 2986

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active

044080859

ABSTRACT:
A process for producing sec-butanol and sec-butyl tert-butyl ether from butane comprises: (a) partially isomerizing n-butane to produce a mixture of n-butane and isobutane; (b) catalytically dehydrogenating said butanes to produce a mixture containing at least butene-1, isobutene and butadiene; (c) selectively hydrogenating butadiene and converting butene-1 to butene-2; (d) etherifying isobutene contained in the dehydrogenation reaction mixture with sec-butanol to form a mixture of sec-butyl tert-butyl ether and unreacted hydrocarbons; (e) converting butene-2 from the unreacted hydrocarbon mixture by hydration to produce sec-butanol; (f) recycling said sec-butanol to the etherification step; recovering said sec-butyl tert-butyl ether.

REFERENCES:
patent: 3119766 (1964-01-01), Voltz et al.
patent: 3726942 (1973-04-01), Louder
patent: 3912463 (1975-10-01), Kozlowski et al.
patent: 4252541 (1981-02-01), Herbstman
patent: 4329516 (1982-05-01), Al-Muddarris

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