Process for preparing prostaglandins

Details Process for preparing prostaglandins Process for preparing prostaglandins

1991-01-17

1991-12-24

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

560 53, 560121, 562463, 562503, 568379, C07C17700

Patent

active

050754785

ABSTRACT:
A process for preparing prostaglandin derivatives by reacting a trans bis-tin ethylene with an organo metal compound then with a compound selected from an epoxide, aldehyde, or ketone, then, without isolation and in the same reaction vessel, reacting with an organo lithium compound, a cuprate complex and a cyclopentenone to produce a prostaglandin intermediate having an unprotected hydroxyl group on the omega side chain.

REFERENCES:
Kitano, Chemistry Letters, 1987, 1523.
Behling, J., A.C.S. 110, 2642 (1988).

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