Process for preparing polyethylene naphthalate based polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528185, 528277, 528281, 528283, 528285, 528286, 528298, 528302, 528308, 5283086, C08G 6378, C08G 6302

Patent

active

060404175

ABSTRACT:
A process for preparing polyethylene naphthalate polymer by using a composite catalyst. The process comprises the steps of esterifying a dicarboxylic acid containing 2,6-NDCA, a dicarboxylic ester containing 2,6-NDC or derivatives thereof, with ethylene glycol or a glycol containing ethylene glycol to produce esterification polymers containing bis(beta-hydroxyethyl)naphthalate; continuously polycondensing the obtained esterification polymers to prepare a polymers of polyethylene naphthalate; and wherein the process includes using a composite polymerization catalyst, said composite polymerization catalyst comprising a titanium compound, a phosphorous compound and optionally an antimony compound. The process can considerably reduce both the esterification time and the polycondensation time and provides a good color and excellent physical characteristics.

REFERENCES:
patent: 5286836 (1994-02-01), Park et al.
patent: 5714570 (1998-02-01), Kim et al.

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