Process for preparing polyene compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604055, 2604658R, 260476R, 260479R, 260479S, 260483, 260484P, 260485R, 260488H, 260535P, 260537N, 260546, 260561K, 260561N, 260614R, 2606315, C07C 6700

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039392023

ABSTRACT:
Polyene compounds of the formula: ##EQU1## wherein R' is protected or unprotected hydroxyl or a group of the formula: ##EQU2## (in which R" and R"' are each carboxyl or a group convertible into carboxyl on hydrolysis), m is a positive integer and n is 0 or a positive integer, which are useful as intermediates in the synthesis of coenzyme Q, can be produced advantageously through a step for the dehydration of a compound of the formula: ##EQU3## wherein R', m and n are each as defined above.

REFERENCES:
wagner et al., Synthetic Organic Chemistry, John Wiley & Sons Inc. (New York) 1953, pp. 32 and 149.
Fieser et al., Advanced Organic Chemistry, Reinhold Publishing Corp. (New York), 1961, p. 140.

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