Organic compounds -- part of the class 532-570 series – Organic compounds – Azides
Patent
1992-11-23
1995-08-15
Richter, Johann
Organic compounds -- part of the class 532-570 series
Organic compounds
Azides
552 10, C07F 928
Patent
active
054420806
ABSTRACT:
The invention concerns a process of preparation of the polyazido alcohols by reaction of a polysubstituted oxirane having in position .beta. a nucleofuge group with a metal nitride, characterized in that the reaction is performed in an aqueous medium.
The oxirane formula is: ##STR1## in which X represents a nucleofuge substituent, R1 represents an atom of hydrogen, a lower alkyl group substituted or not by a halogen, an aryl group possibly substituted, R2 and R3 represent an atom of hydrogen, a lower alkyl radical possibly substituted, an aryl group possibly substituted, R4 represents an atom of hydrogen, a lower alkyl group possibly substituted, an aryl group possibly substituted by an alkoxy group. Application to the preparation of polyamino alcohols, ureas, polyazidothiols and binding compositions for propergols.
REFERENCES:
Patterson, A French-English Dictionary for Chemists, 2nd Ed., pp. 38-39 (1954).
Cotton, et al., Advanced Inorganic Chemistry, 2nd Ed., p. 331 (1966).
Hach's Chemical Dictionary, 4th Ed., p. 457 (1972).
McGraw-Hill Dictionary of Chemical Terms, Sybil Parker, ed. p. 380 (1984).
Mansion I. E. Harrap's Standard French & English Dictionary, p. A:87 (1980).
Edgar R. Wilson et al., J. Chem. Eng. Data, Oct. 1982, vol. 27, No. 4, pp. 472-473.
C. A. VanderWerf et al., J. Amer. Chem. Soc., Mar. 6, 1954, vol. 76, No. 4, pp. 1231-1235.
Caubere Paul
Forconi Herve
Etat Francais (represente par le Delegue General pour l'Armement
Kestler Kimberly J.
Richter Johann
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