Process for preparing polyalkylene oxide having narrow distribut

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

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C08G 6512

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active

046544178

ABSTRACT:
Polyalkylene oxide having narrow distribution of molecular weight is prepared by a process comprising polymerizing alkylene oxide in the presence of a complex produced by the reaction of an organoaluminum compound with a porphyrin compound and an active hydrogen-containing compound.

REFERENCES:
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patent: 4565845 (1986-01-01), Inoue et al.
Aida et al., "Living Polymerization of Epoxide", Macromolecules 14, 1166 (1981).
Takuzo Aida et al., Polymerization of Epoxides Catalysed by Metalloporphine from Makromol Chem., vol. 182, pp. 1073-1079, (1981).

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