Process for preparing poly(organophosphazenes) from soluble or g

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528228, 528243, 528246, 528266, 528361, 528362, 528363, 528374, 528378, 528380, 528391, 528392, 528399, C08G 7902, C08G 7300

Patent

active

042269725

ABSTRACT:
Poly(organophosphazenes) containing repeating units of the structure: ##STR1## wherein X and X' represent organic substituents which may be the same or different and n is from 20 to 50,000, are prepared by a process which involves reacting a poly(dichlorophosphazene) having the formula --(NPCl.sub.2).sub.n --, in which n is from 20 to 50,000, with an active hydrogen-containing compound in the presence of a bicyclic amidine represented by the structure: ##STR2## in which m is an integer of from 1 to 10. A unique aspect of the process of the invention is that it can be utilized to prepare such poly(organophosphazenes) utilizing either soluble or gelled (insoluble) poly(dichlorophosphazenes) as starting materials.

REFERENCES:
patent: 3893980 (1975-07-01), Allcock et al.

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