Process for preparing perfluoropolyethers

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568614, C07C 4330

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active

054881811

ABSTRACT:
Process for preparing peroxidic perfluoropolyethers by oxidation of tetrafluoroethylene with oxygen, in liquid phase comprising a solvent and in the presence of a chemical initiator, at a pressure between 2 and 15 absolute atm and operating with a molar ratio of the tetrafluoroethylene to the chemical initiator higher than 35. The process allows to increase the molecular weight of the perfluoropolyethers at the same content of peroxidic oxygen.

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patent: 3847978 (1974-11-01), Sianesi et al.
patent: 4085137 (1978-04-01), Mitsch et al.
patent: 5144092 (1992-09-01), Marraccini et al.
patent: 5220076 (1993-06-01), Marraccini et al.

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