Process for preparing penicillin sulfoxides

Details Process for preparing penicillin sulfoxides Process for preparing penicillin sulfoxides

1979-03-26

1980-10-28

Trousof, Natalie

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2602452R, C07D49904

Patent

active

042306205

ABSTRACT:
A penicillin is treated with a peroxymonosulfate at a temperature of from about 0.degree. C. to about 50.degree. C. in an aqueous medium to produce a penicillin sulfoxide.

REFERENCES:
patent: 3197466 (1965-07-01), Chow et al.
patent: 3544581 (1970-12-01), Essery
patent: 3586667 (1971-06-01), Hatfield
patent: 4052387 (1977-10-01), Kukolja
patent: 4081440 (1978-03-01), Kukolja
Kennedy et al., J. Org. Chem., 25, 1905-1906, (1960).
Chow et al., J. Org. Chem., 27, 1381-1383, (1962).
Barton et al., J. Am. Chem. Soc., 91, 1529-1530, (1969).
Cooper et al., J. Am. Chem. Soc., 91, 1408-1415, (1969).
Spry, J. Am. Chem. Soc., 92, 5006-5008, (1970).
Spry, J. Org. Chem., 37, 793-795, (1972).

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