Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1998-06-04
1998-11-24
Burn, Brian M.
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
564434, C07C20936
Patent
active
058409823
ABSTRACT:
An improvement in a process for the preparation of a p-aminodiarylamine by reduction of the corresponding nitroso or nitro compound with hydrogen in a hydrogenator in the presence of a catalyst is disclosed. The invention includes equipping the hydrogenator with filtration means capable of separating the p-aminodiarylamine product from the catalyst, whereby the p-aminodiarylamine product can be removed from the hydrogenator while the catalyst is retained therein, thereby permitting the reaction to be run semicontinuously or continuously.
REFERENCES:
patent: 2974169 (1961-03-01), Newby et al.
patent: 3728392 (1973-04-01), Levy et al.
patent: 4122118 (1978-10-01), George et al.
patent: 4140716 (1979-02-01), Maender et al.
patent: 4155936 (1979-05-01), Sturm
patent: 4169146 (1979-09-01), Katsube et al.
patent: 4187248 (1980-02-01), Merten et al.
patent: 4187249 (1980-02-01), Maender et al.
patent: 4196146 (1980-04-01), Merten et al.
patent: 4209463 (1980-06-01), Maender et al.
patent: 4313002 (1982-01-01), Symon et al.
patent: 4479008 (1984-10-01), Batorewicz et al.
patent: 4518803 (1985-05-01), Batorewicz et al.
patent: 4614817 (1986-09-01), Maender et al.
patent: 4670595 (1987-06-01), Podder et al.
patent: 4683332 (1987-07-01), Sturm
patent: 5117063 (1992-05-01), Stern et al.
patent: 5420354 (1995-05-01), Malz et al.
patent: 5574187 (1996-11-01), Malz et al.
Gerard V. Smith et al., "Hydrogenation of Nitrosobenzene over Palladium Catalysts," in Catalysis of Organic Reactions, Thomas A. Johnson and John R. Kosak, eds. (Marcel Dekker, New York, 1993), pp. 137-149.
Gerard V. Smith et al., "Hydrogenation and Dehydrohalogenation of .rho.-Chloronitrobenzene: Effect of Pd Metal Particle Size on Activity and Selectivity," in Catalysis of Organic Reactions, Mike G. Scaros and Michael L. Prunier, eds. ((Marcel Dekker, New York, 1995), pp. 469-474.
Malz Russell E.
Reynolds Michael
Burn Brian M.
Grandinetti Paul
Thompson Raymond D.
Uniroyal Chemical Company, Inc.
LandOfFree
Process for preparing para-phenylenediamine derivatives does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for preparing para-phenylenediamine derivatives, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing para-phenylenediamine derivatives will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1704538