Process for preparing organotin trihalides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 722

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active

041675207

ABSTRACT:
This invention provides a process for preparing organotin trihalides which comprises reacting tin tetrahalide with an organotin dihalide of general formula R.sub.2 SnHal.sub.2 wherein Hal denotes a halogen atom and R represents the group ##STR1## wherein R', R", R'" and R"" are each independently a hydrogen atom or an alkyl or substituted alkyl group having 1 to 18 carbon atoms with the proviso that at least one of R' and R" contains adjacent to the group HC-- a carbonyl group which forms a part of an acid group, ester group, aldehyde group, acid halide group or ketone group, and recovering the organotin trihalide of formula RSnHal.sub.3 thereby formed.

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Omae et al, J. Organometallic Chem., 24, pp. 663-666, (1970).
Matsuda et al, J. Organometallic Chem., 25, pp. 101-109, (1970).
Sawyer, Organotin Compounds, Marcel Dekker Inc., N.Y., pp. 90 & 91, (1971).

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