Process for preparing organophosphines

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415773, C07F 900

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active

052845559

ABSTRACT:
Olefins can be induced to react with phosphines at ambient temperature and pressure to produce organophosphines by free-radical addition. Suitable olefins include C.sub.1 to C.sub.4 alpha-olefins, cyclic olefins, polycycloalkenyl species, allyl alcohol and esters of vinyl phosphonic acid.

REFERENCES:
patent: 2803597 (1957-08-01), Stiles et al.
patent: 3435076 (1969-03-01), Mason et al.
patent: 4613699 (1986-09-01), Green
Rauhut et al, J. Org. Chem., vol. 26, pp. 5138 and 5140; vol. 24, p. 5144.

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