Process for preparing organic pentavalent phosphorus compounds

Details Process for preparing organic pentavalent phosphorus compounds Process for preparing organic pentavalent phosphorus compounds

1997-11-10

1999-07-06

Ambrose, Michael G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus esters

564 12, 564 13, 568 12, 568 14, C07F 909

Patent

active

059199687

ABSTRACT:
A process for preparing an organic pentavalent phosphorus compound comprising oxidizing an organic trivalent phosphorus compound with an aqueous hydrogen peroxide solution in the presence of an inorganic or organic base at a temperature of 0.degree. C. to 50.degree. C. to obtain the corresponding organic pentavalent phosphorus compound.

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Barton, Derek H.R. et al. "Catalysis of the Oxidation of Triphenylphosphine and of Trimethyl Phosphite by Hydrogen Peroxidein the Presence of Fe(III) Compounds" Tetrahedron Letters 38(10), 1711-12 (1997).
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CADOGAN, "Oxidation of Tervalent Organic Compounds of Phosphorus", Quart. Rev., 16, pp. 208-239 (1962).

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