Chemistry: molecular biology and microbiology – Process of utilizing an enzyme or micro-organism to destroy... – Resolution of optical isomers or purification of organic...
Patent
1998-08-19
1999-11-23
Lilling, Herbert J.
Chemistry: molecular biology and microbiology
Process of utilizing an enzyme or micro-organism to destroy...
Resolution of optical isomers or purification of organic...
435128, 435130, 435131, 435195, 435198, C12P 4100, C12P 1100, C12P 1300
Patent
active
059899000
ABSTRACT:
A process for preparing optically active allylic alcohol derivatives comprises reacting a racemic mixture of the following formula I ##STR1## wherein R is alkyl, alkenyl, or substituted or unsubstituted aryl or arylalkyl;
with acetate or anhydride under the catalysis of Pseudomonase AK, PS or K-10 lipase in the presence of an organic solvent.
REFERENCES:
patent: 5106750 (1992-04-01), Wong et al.
Caddick, S.;Jenkins, K. Chem. Soc. Rev. 1996, 447-456.
Noyori R.; Tokunaga, M.; Kitamura M. Bull. Chem. Soc. Jpn. 1995, 68, 36-55.
Ward, R.S. Tetrahedron: Asymmetry 1995, 6, 1475-1490.
Burgess, K.; Jennings, L.D. J. Am. Chem. Soc. 1991, 113, 6129-6139.
Mitsuda, S.; Nabeshima, S. Recl. Trav. Chim. Pays-Bas 1991, 110, 151-154.
Burgess, K.; Jennings, L.D.. J. Am. Chem. Soc. 1990, 112, 7434-7436.
Panek, J.S.; Clark, T.D. J. Org. Chem. 1992, 57, 4323-4326.
Noyori, R.; Suzuki, M. Angew. Chem. Int. Ed. Engl. 1984, 23, 847-876.
Caton, M.P.L. Tetrahedron 1979, 35, 2705-2742.
Taylor, R.J.K. Synthesis 1985, 364-392.
Samuelsson, B., Angew. Chem. Int. Ed. Engl. 1983, 22, 805-815.
Vane, J.R. Angew. Chem. Int. Ed. Engl. 1983, 22, 741-752.
Bergstorm, S. Angew. Chem. Int. Ed. Engl. 1983, 22, 858-866.
Nelson, N.A.; Kelly, R.C.; Johnson, R.A. Chem. Eng. News 1982 33(60), 30-44.
Roberts, S.M.; Scheinmann, F. New Synthetic Routes to Prostaglandins and Thromboxanes, Academic Press: New York 1982.
Newton, R.F.; Roberts, S.M. Tetrahedron 1980, 36, 2163-2196.
Nicolaou, K.C.; Gasic, G.P.; Barnette, W.E. Angew. Chem. Int. Ed. Engl. 1978, 17, 293-312.
Mitra, A. Synthesis of Prostaglandins, Wiley-Interscience: New York, 1977.
Gooding, O.W.; Beard, C.C.; Cooper, G.F.; Jackson, D.Y. J. Org. Chem. 1993, 58, 3681-3686.
Gooding, O.W. J. Org. Chem. 1990, 55, 4209-4211.
Suzuki, M.; Yanagisawa, A.; Noyori, R.J. Am. Chem. Soc. 1988, 110, 4718-4726.
Suzuki, M.; Yanagisawa, A.; Noyori, R.J. Am. Chem. Soc. 1985, 107,. 3348-3349.
Morita, Y.; Suzuki, M.; Noyori R. J. Org. Chem. 1989, 54, 1785-1878.
Pirkle, W.H. Asymmetric Synthesis, Morrison J.D. ed., Academic Press: New York, 1983, vol. 1, pp. 125-152; and Williams, A.; Ibrahim, I.T. Chem. Rev. 1981, 81, 589-636.
Chen Shyh-Fong
Ku Hao
Lee Adam Shih-Yuan
Pan Ohm-Guo
Yeh Hsiu-Chih
Development Center of Biotechnology
Lilling Herbert J.
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