Process for preparing nitrogen compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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252609, C07C 4561

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active

043283578

ABSTRACT:
(Cyclo)alkylenediammonium compounds corresponding to the formula: ##STR1## wherein X is halogen, R is an alkylene or cycloalkylene group containing 2-15 carbon atoms, each R' alone is an alkyl, cycloalkyl, or aralkyl group, and R'-R' together represent an alkylene, cycloalkylene, or aralkylene group are prepared by esterifying a tetrahalophthalic anhydride with a mono- or dihydroxyalkane, -cycloalkane, or -aralkane having a boiling point below 250.degree. C. to form a half-ester and then reacting the half-ester with a stoichiometric amount of a diaminoalkane or diaminocycloalkane containing 2-15 carbon atoms.
The (cyclo)alkylenediammonium compounds of the invention are useful as flame retardants for normally flammable organic polymers and also have utility as intermediates for the preparation of N,N'-(cyclo)alkylene-bis-tetrahalophthalimides, which are also useful as flame retardants. The imides are prepared simply by heating the diammonium compounds.

REFERENCES:
patent: 4092345 (1978-05-01), Wolford et al.
Matsuda et al., Japanese Kokai 76 16607 as cited in Chem. Abstracts 85, 20871t (1976).
Hattori, Japanese 22, 479 (65) as cited in Chem. Abstracts 64 3757g (1966).

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