Process for preparing methyltin chlorides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 722

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041285654

ABSTRACT:
Improved process for preparing methyltin chlorides through direct reaction of methyl chloride with metallic tin wherein the reaction is effected in a high-boiling hydrocarbon solvent in the presence of a glycol and iodine or an iodine compound as a reaction accelerator.

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patent: 3519665 (1970-07-01), Molt et al.
patent: 3547965 (1970-12-01), Takubo et al.
Smith et al., J. A. C. S., 75, pp. 4103-4106, (1953).
Sisido et al., J. Arganometal, Chem. 9, pp. 109-115, (1967).
Oakes et al., J. Arganometal, Chem. 3, pp. 472-477, (1965).

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