Process for preparing methyl jasmonate and related compounds

Details Process for preparing methyl jasmonate and related compounds Process for preparing methyl jasmonate and related compounds

1974-03-01

1977-03-29

Gerstl, Robert

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260483, C07C 6974, C07C 6730

Patent

active

040149196

ABSTRACT:
Methyl dl-jasmonate and related compounds, which are useful in perfumery, are synthesized by alkylation of a 2-carbo(lower alkoxy)-3-oxocyclopentaneacetic acid lower alkyl ester. A new method for the synthesis of the intermediates, 2-carbo(lower alkoxy)-3-oxocyclopentene-1-acetic acid lower alkyl esters, is also described.

REFERENCES:
house, Modern Synthetic Reactions, 2nd Ed. pp. 756-761 (1973).
Ireland et al., JACS 81, 2907 (1959).
House, Modern Synthetic Reactions, 2nd Ed. pp. 10, 14, 516-518, 641-643, 762-765 (1973).
March, Advanced Organic Chem. pp. 350-361, 364, 477-481, 592-596, 642-645 (1969).

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