Process for preparing methacrylic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562534, 562535, 562536, 502209, 502211, C07C 5125, C07C 57055

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active

044409486

ABSTRACT:
Methacrylic acid is prepared by reacting methacrolein with molecular oxygen in the vapor phase at a temperature of from 230.degree. C. to 450.degree. C. in the presence of a catalyst having the formula Mo.sub.12 P.sub..alpha.' X.sub..beta.' Y.sub..gamma.' O.sub..delta.' wherein X is at least one member of the group consisting of Cs and Tl:Y is at least one member of the group consisting of Cs and Tl; Y is at least one member of the group consisting of V, Zr, Nb, Ni, Ta and Fe; .alpha.'=0.1-3; .beta.'=0.2-9; .gamma.'=0.1-7; .delta.'=36-100.

REFERENCES:
patent: 3875220 (1975-04-01), White et al.
patent: 3925464 (1975-12-01), Oda et al.
patent: 3976688 (1976-08-01), Akiyama et al.
patent: 4075244 (1978-02-01), Akiyama et al.

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