Process for preparing manganese complexes

Details Process for preparing manganese complexes Process for preparing manganese complexes

1992-07-06

1993-12-28

Shah, Mukund J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

502150, 502160, 502167, 540465, 546 2, 548111, 5483127, 5483651, 556 46, 556 49, C07F 1300, B01J 3122

Patent

active

052741478

ABSTRACT:
A process for preparing a dinuclear manganese complex of formula (A) ##STR1## wherein: Mn represents manganese in the III or IV oxidation state, each X is independently a co-ordinating or bridging species selected from H.sub.2 O, O.sub.2.sup.-, O.sup.2-, OH.sup.-, SH.sup.-, S.sup.2-,>S=O, Cl.sup.-, N.sub.3.sup.-, SCN.sup.-, N.sup.3-, RCOO.sup.-, NH.sub.2.sup.- and NR.sub.3 where R is hydrogen, alkyl or aryl (optionally substituted);

REFERENCES:
patent: 4728455 (1988-03-01), Rerek
patent: 5153161 (1992-10-01), Kerschner et al.
K. Wieghardt, "Journal of the American Chemical Society", 1988, vol. 110, No. 22, p. 7398.
"Journal of the Chemical Society--Chemical Communications", 1985, p. 1145.

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