Process for preparing linear alpha-olefins using zirconium adduc

Details Process for preparing linear alpha-olefins using zirconium adduc Process for preparing linear alpha-olefins using zirconium adduc

1988-05-18

1989-08-08

Pal, Asok

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By addition of entire unsaturated molecules, e.g.,...

585512, C07C 226

Patent

active

048555258

ABSTRACT:
Linear alpha-olefins are prepared by the oligomerization of ethylene using a two component catalyst system comprising (a) a soluble adduct of zirconium tetrahalide, the halogen being Br or Cl, with an organic compound selected from the group of esters, ketones, ethers, amines, nitriles, anhydrides, acid chlorides, amides or aldehydes, the organic compound having up to about 30 carbon atoms and (b) an alkyl metal selected from the group R.sub.2 AlX. RalX.sub.2, R.sub.3 Al.sub.2 X.sub.3, R.sub.3 Al and R.sub.2 Zn where R is C.sub.1 -C.sub.20 alkyl and X is Cl or Br. ZrCl.sub.4 adducts with organic acetates are the preferred embodiments.

REFERENCES:
patent: 3622552 (1971-11-01), Fukuda et al.
patent: 4361714 (1982-11-01), Langer et al.
patent: 4377720 (1983-03-01), Langer
patent: 4396788 (1983-08-01), Langer
patent: 4409409 (1983-10-01), Langer et al.
patent: 4410750 (1983-10-01), Langer
patent: 4434312 (1984-02-01), Langer
patent: 4434313 (1984-02-01), Langer
patent: 4442309 (1984-04-01), Langer
patent: 4486615 (1984-12-01), Langer
Kletenik et al., Zkur, Obschchel, Kim 29, 13-17 (1959).
Graven et al., J. Inorg, Nucl. Chem. 31(C), 1743-1748 (1969).
Hummers et al., J. Am. Chem. Soc. 74, 5277-5279 (1952).
Langer, J. Macromol. Sci-Chem. A4(4), pp. 775-787 (Jul. 1970).
Kirk-Othmer, Encyc. of Chem. Technology, 3rd Edition, vol. 16, pp. 487-499 (1981:John Wiley & Sons, Inc.).
Boor, Ziegler-Natta Catalysts and Polymerizations, (NY:Academic Press, 1978) p. 228.

Affiliated with

Also associated with

Rating

Process for preparing linear alpha-olefins using zirconium adduc does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing linear alpha-olefins using zirconium adduc, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing linear alpha-olefins using zirconium adduc will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-907394