Process for preparing L-rhamnose

Sugar – starch – and carbohydrates – Processes – Carbohydrate manufacture and refining

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127 43, 127 44, 127 461, 127 34, 127 53, 127 55, 127 56, 127 58, 536128, C13K 100, C13D 100, C13D 114, C13J 106

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047582839

ABSTRACT:
This invention relates to a process for readily and efficiently preparing L-rhamnose with the use of a marine alga belonging to the family Monostromaceae, Ulvales.
According to the process of the present invention, rhamnan sulfate is extracted from a marine alga belonging to the family Monostromaceae such as Monostroma nitidium Wittrock and the obtained extract is hydrolyzed by adding acid(s) thereto followed by heating or treating thereof with a cation exchange resin followed by heating to thereby give a solution containing free L-rhamnose.
Since the solution thus obtained contains a large amount of salts, the removal of these salts is significantly important in the preparation of L-rhamnose. In the present invention, an effective process therefor is combined with a conventional method by using an ion exchange resin to thereby establish an efficient desalting process.
Further it is effective to elevate the purity of L-rhamnose by adding baker's yeast, which selectively ferments various sugars, to the solution containing L-rhamnose.

REFERENCES:
patent: 3240755 (1966-03-01), Schweiger
patent: 3856569 (1974-12-01), Strong
W. Pigman et al., The Carbohydrates, vol. IIB, 2nd ed., 1970, pp. 561-563.
Chemical Abstracts, vol. 90, 1979, p. 274, Abstract No. 100140x.
Chemical Abstracts, vol. 51, No. 4, 1957, Abstract No. 2955i.
Chemical Abstracts, vol. 95, 1981, p. 320, Abstract No. 192055c.

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