Process for preparing internal olefins

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By double-bond-shift isomerization

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C07C 523, C07C 525

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048779180

ABSTRACT:
A process for isomerizing an olefin to an internal olefin in the presence of a solid base which is obtainable by heating an alkali metal hydride and alumina, wherein the alumina has been pretreated with at least one salt selected from the group consisting of alkali metal carbonates and alkali metal aluminates, in an atmosphere of an inert gas at a temperature of 200 to 450.degree. C.

REFERENCES:
patent: 2361613 (1944-10-01), Drennan
patent: 3201493 (1965-08-01), Meisinger
patent: 3204009 (1965-08-01), Keith
patent: 3501395 (1970-03-01), Miale
patent: 4205192 (1980-05-01), Harada

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