Process for preparing hydrogels as spherical beads of large size

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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525 10, 525440, 525920, 526172, 526234, 526279, 526321, 525424, 525455, 525925, 525404, 525426, 525445, 525479, 525921, 526226, 526259, 526317, 526909, 526221, 526227, 526237, 526260, 526303, 526320, 526332, 526910, C08F 218

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042244277

ABSTRACT:
The disclosure describes an improved process for the preparation of uniform, spherical beads of up to 5 mm diameter of a crosslinked, water-insoluble hydrogel by suspension polymerization in a concentrated aqueous salt solution of 95-30% by weight of a monoolefinic water-soluble monomer containing at least 5% of a hydroxy substituted hydrophilic vinyl monomer with 5-70% by weight of a terminal diolefinic macromer crosslinking agent in the presence of water-insoluble, gelatinous, strong water-bonding inorganic metal hydroxides as suspending agents in the absence of excess alkali. The hydrogels have a host of pharmaceutical and industrial uses.

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patent: 3996308 (1976-12-01), Douek et al.
patent: 4034017 (1977-07-01), Chang et al.
patent: 4041104 (1977-08-01), Selley

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