Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1977-03-10
1979-03-27
Garner, Vivian
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
204180P, C07C 5126
Patent
active
041467310
ABSTRACT:
Improved process for preparing glyoxylic acid by oxidizing glyoxal with nitric acid at a concentration of 4 to 10% by weight of nitric acid based on the weight of the reaction system, introducing oxygen or oxygen-containing gas into the reaction system so as to satisfy a relation K.sub.L a.P.gtoreq.150, wherein K.sub.L a is a liquid-phase over-all mass transfer coefficient of the reactor (1/hour) and P is a partial pressure of oxygen in the reaction system (kg./cm..sup.2). Glyoxylic acid can be prepared in high yields with less consumption of nitric acid and the generation of nitrogen oxides can be remarkably decreased.
REFERENCES:
patent: 3281460 (1966-10-01), Gandon
Ogahara Junzo
Sekiyama Kunihiko
Garner Vivian
Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
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