Process for preparing glycols and glycol esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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568860, C07C 6705, C07C 2903

Patent

active

043249094

ABSTRACT:
In the process for catalytically reacting olefin and oxygen to provide glycol or a mixture of glycol and glycol ester, higher rates of reaction and/or higher selectivities for the desired product(s) are obtained employing as catalyst, a composition comprising a mixture of molecular iodine and hydrobromic acid; hydriodic acid and hydrobromic acid; or, at least one oxide of antimony, bismuth or tellurium in admixture with at least one member of the group consisting of hydriodic acid; molecular iodine; hydriodic acid and molecular iodine; molecular iodine and hydrobromic acid; and, hydriodic acid and hydrobromic acid in a water or water-carboxylic acid reaction medium.

REFERENCES:
patent: 3479395 (1969-11-01), Huguet
patent: 3985795 (1976-08-01), Kollar
patent: 4095037 (1978-06-01), Stapp
patent: 4195190 (1980-03-01), Bierschenk et al.
patent: 4202995 (1980-05-01), Mee
patent: 4205181 (1980-05-01), Murib
patent: 4219666 (1980-08-01), Platz et al.

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