Process for preparing furan compositions

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549484, C07D30732

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active

051030268

ABSTRACT:
A process for preparing a composition of the formula ##STR1## by reacting a composition of the formula ##STR2## with a polyhydric alcohol of the formula HO--X--OH in the presence of an acid catalyst at an elevated temperature to form a ketal of the formula ##STR3## and reacting the ketal of the formula (II) with a monohydric alcohol in the presence of an acid at an elevated temperature to form ##STR4##

REFERENCES:
patent: 4681703 (1987-07-01), Harris et al.
Chemical Abstract 99:158162h p. 593 (1983).
Journal of Organic Chemistry, vol. 52, 1987, American Chemical Society (U.S.), T. Hosokawa et al., "Palladium(II)-Catalyzed Acetalization of Terminal Olefins Bearing Electron-Withdrawing Substituents . . . Diols", pp. 1758-1764.
Julius Grant, Hackh's Chemical Dictionary Fourth Edition, p. 101.
Korte et al., Chemische Benichte, 90, 2137-2149, (1957).
Korte et al., Angewante Chemie, No. 23, pp. 709-752, (1959).
Green, "Protective Groups in Organic Synthesis", pp. 114-129, John Wiley & Sons, New York (1981).

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