Process for preparing electrically conductive polymer

Details Process for preparing electrically conductive polymer Process for preparing electrically conductive polymer

1986-07-30

1988-09-06

Barr, Josephine

Chemistry: electrical and wave energy

Processes and products

204 72, 204 78, 204291, 252500, 252512, 252513, 252514, 252518, C25C 1100, H01B 106

Patent

active

047691158

ABSTRACT:
An electrically conductive polymer is produced by dissolving or dispersing a monomer of an aromatic compound or a derivative thereof and an electrolyte in an organic polar medium, effecting an electrochemical, anodic oxidation in the resulting solution or dispersion, in the presence of one or more metal ions, to obtain an electrically conductive polymer, and separating the obtained polymer. The metal ion is being selected from the group consisting of a copper ion, bivalent silver ion, trivalent iron ion, trivalent manganese ion, a ruthenium ion, a rhenium ion and a rhodium ion. Films of the polymer have high conductivity.

REFERENCES:
patent: 4546010 (1985-10-01), Keller et al.
patent: 4566955 (1986-01-01), Naarmann
patent: 4582587 (1986-04-01), Hotta et al.
patent: 4585581 (1986-04-01), Skotheun
patent: 4604427 (1986-08-01), Roberts et al.
patent: 4617143 (1986-10-01), Kossmehl et al.
patent: 4622169 (1986-11-01), Rickle
Polymerization of Benzene by Peter Kovacic et al., pp. 454-458 (1962).
Electrochemical Doping of Poly(p--phenylene) by L. W. Shacklette et al.-pp. 361-362 (1982).
Electrochemical Preparation of High Quality Poly by M. Satoh et al.-pp. 1629-1630 (1985).
Electrochemical Polymerization of Benzene by Kyozi Kaeriyama-pp. 1199-1200 (1984).
Electrochemical Polymerization of Napthalene by M. Satoh et al.-pp. 550-551 (1986).
Electrochemical Polymerization of Anthracene by M. Satoh et al.-pp. 979-980 (1986).

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