Process for preparing E-isomer of triazolyl styryl ketone deriva

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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568310, C07D24912

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active

048144606

ABSTRACT:
A novel process for preparing the E-isomer of triazolyl styryl ketone derivative of the formula (I): ##STR1## is disclosed. The process includes treating the Z-isomer of the derivative which may contain the E-isomer of the derivative with an acid and an isomerization catalyst in an organic solvent, precipitating and separating the resulting salt of E-isomer from the solution, and decomposing the resulting precipitate to obtain the E-isomer of the derivative free from the acid. The E-isomer is useful for preparing the E-isomer of triazolyl styryl carbinol of the formula (II): ##STR2## which is useful as an antimicrobial agent, a herbicide, a plant growth regulator, or the like.

REFERENCES:
patent: 4018718 (1977-04-01), Ochsner et al.
Baranyai et al., "Determination of the Geometric, etc.", CA 95: 169538d (1981).
Cobb et al., "Isomerization of Cis, Trans, etc.", CA 97: 200936t (1977).

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