Process for preparing dl-cis-1-hydroxy-3-substituted-6,6-dimethy

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D31178

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041488091

ABSTRACT:
Reaction of a 5-substituted resorcinol with a 1-alkoxy-4-(1-hydroxy-1-methylethyl)-1,4-cyclohexadiene in the presence of a suitable catalyst affords the corresponding dl-cis-1-hydroxy-3-substituted-6,6-dimethyl-6,6a,7,8,10,10a-hexahydro-9H-d ibenzo[b,d]pyran-9-one.

REFERENCES:
patent: 4054582 (1977-10-01), Blanchard et al.
Archer et al., J. Org. Chem., 42, 2277 (1977).
Razdan et al., Jacs, 96, 5860 (1974).
Razdan et al., Tetrahedron Letters, pp. 4947-4950 (1969).

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