Process for preparing diperoxide from an organic hydro-peroxide

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C17902

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039352781

ABSTRACT:
Diperoxides, useful as free radical type polymerization initiators, for example, are preparable from an organic hydroperoxide such as t-butyl hydroperoxide, and a ketone using catalyst comprising molybdenum or vanadium.

REFERENCES:
patent: 2455569 (1948-12-01), Dickey
patent: 2537853 (1951-01-01), Pezzaglia
patent: 3434975 (1969-03-01), Sheng
Dickey et al., "J. Amer. Chem. Soc." Vol. 71, pp. 1432-1434

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