Process for preparing dimethyl vinylphosphonate from dimethyl 2-

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

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C07F 940

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057636370

ABSTRACT:
The invention relates to a process for preparing dimethyl vinylphosphonate by thermal dissociation of dimethyl 2-acetoxyethanephosphonate in the gas phase, which comprises vaporizing dimethyl 2-acetoxyethanephosphonate and dissociating it without catalysis at a temperature of from 400.degree. to 700.degree. C. into dimethyl vinylphosphonate and acetic acid.

REFERENCES:
patent: 4388252 (1983-06-01), Dursch et al.
patent: 4894470 (1990-01-01), Roscher et al.
patent: 5132444 (1992-07-01), Northemann et al.
Chemical Abstracts, vol. 078, No. 5, p. 517, Feb. 5, 1973, Columbus, Ohio, U.S., abstract No. 029900, Yamagami M et al: "Induced addition of dialkyl phosphites to olefins and pyrolysis of the 1:1 adducts".

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