Process for preparing diesters of dicarboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560114, 560131, 560139, 560144, 560146, 560193, 560198, 560204, C07C 6738

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041385802

ABSTRACT:
A process for preparing a diester of a dicarboxylic acid having two more carbon atoms than the unsaturated hydrocarbon used as a starting material, which comprises subjecting an unsaturated hydrocarbon, carbon monoxide and an alcohol to reaction in the presence of a platinum group metal in combination with one or more compounds selected from the group consisting of nitric acid, a nitrogen oxide and an ester of nitrous acid.

REFERENCES:
patent: 3397226 (1968-08-01), Fenton
patent: 3530168 (1970-09-01), Biale
patent: 3625995 (1971-12-01), Brattesoni
patent: 3755421 (1973-08-01), Fenton et al.
J. Org. Chem. 37, No. 12, 2034-2035, (1972).
Derwent Abstract Jap. Pat. Provisional Publn. SHO-49-66619/1974.
Derwent Abstract Jap. Pat. Provisional Publn. SHO-49-116018/1974.

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