Process for preparing diaryl methylphosphonate and derivatives t

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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260953, 260982, 260984, C07F 940

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active

041523733

ABSTRACT:
A process is provided for the preparation of diaryl methylphosphonates through the reaction of triaryl phosphites with methanol in the presence of a catalytic quantity of methyl iodide. The reaction is conducted at a temperature of from about 170.degree. C. to about 250.degree. C. New and useful derivatives are produced by reaction of the diaryl methylphosphonates with polyols or amines.

REFERENCES:
arbuzov et al, English Translation of "Bull. Acad. Soci, U.S.S.R., Div. Chem. Sci.", 1954, pp. 361-367.

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