Process for preparing cyclopentadienyl group-containing silicon

Details Process for preparing cyclopentadienyl group-containing silicon Process for preparing cyclopentadienyl group-containing silicon

1994-03-11

1994-11-01

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556 95, C07F 708, C07F 730

Patent

active

053609212

ABSTRACT:
Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.

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Manipulation of Organolanthanide Coordinative Unsaturation, Synthesis, Structures, Structural Dynamics, Comparative Reactivity, and Comparative Thermochemistry of Dinuclear .mu.-Hydrides and .mu.-Alkyls with [.mu.-R.sub.2 Si(Me.sub.4 C.sub.5) (C.sub.5 H.sub.4)].sub.2 Supporting Ligation, J. Am. Chem. Soc. 1990, 112, 9558-9575.

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