Process for preparing cycloaliphatic monoterpenic alcohols

Details Process for preparing cycloaliphatic monoterpenic alcohols Process for preparing cycloaliphatic monoterpenic alcohols

1974-03-07

1976-05-11

Rollins, Alton D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260476C, 260476R, 260489, C07C 3305, C07C 3518

Patent

active

039564045

ABSTRACT:
A process for preparing trans-carveol and perillyl alcohol comprising the oxidation respectively of alpha-pinene and beta-pinene by benzoyl peroxide using a catalyst comprising cuprous/cupric ions, to form the respective benzoate esters, followed by hydrolysis and purification of the resulting alcohols.

REFERENCES:
patent: 2762838 (1956-09-01), Toland
patent: 3210402 (1965-10-01), Kochi
Kochi "J. Am. Chem. Soc.," Vol. 84, pp. 1572-1579 (1962).
Matsubara, J. Chem. Soc. Japan, Vol. 75, pp. 894-896 (1954).
Monsuy, "Doctorial Thesis" Paris 1972 CNRS No. A05077 pp. 94-102, available to public Dec. 23, 1950.

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