Process for preparing ceric carboxylates

Details Process for preparing ceric carboxylates Process for preparing ceric carboxylates

1984-08-06

1986-07-08

Warren, Charles F.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604292, 423 211, 423263, 556 16, C01F 1700, C11C 100

Patent

active

045992010

ABSTRACT:
A process is provided for preparing ceric carboxylates which comprises oxidizing cerous carboxylate with aqueous hydrogen peroxide in a two-phase system comprising an aqueous phase of hydrogen peroxide having a pH of at least 6 and an organic phase comprising a solution of cerous carboxylate in a water-immiscible hydrocarbon solvent at a temperature at which the reaction proceeds but below the temperature of rapid decomposition of hydrogen peroxide, thereby converting cerous to ceric ion and forming a solution of ceric carboxylate in the hydrocarbon solvent; heating the reaction mixture at a temperature at which any ceric-hydrogen peroxide complexes present are decomposed; and separating the organic phase containing ceric carboxylate from the aqueous phase of the reaction mixture.

REFERENCES:
patent: 4231893 (1980-11-01), Woodhead
patent: 4285868 (1981-08-01), Heiba et al.
Comprehensive Inorganic Chemistry, vol. 4, Pergamon Press Ltd., 1973, pp. 97-101, Moeller, Therald, "The Lanthanides: Oxid. State +4".
J. Amer. Chem. Soc., vol. 93, No. 1. Jan. 13, 1971, pp. 995-999, Heiba, E. I., "Oxidation by Metal Salts. VIII. The Decomposition of Ceric Carboxylates in the Presence of Olefins and Arom. Hydrocarbons".

Affiliated with

Also associated with

Rating

Process for preparing ceric carboxylates does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing ceric carboxylates, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing ceric carboxylates will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1450110