Process for preparing calcium thiosulfate solution

Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing

Reexamination Certificate

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C423S562000, C423S566300

Reexamination Certificate

active

06984368

ABSTRACT:
An efficient process to produce calcium thiosulfate (CaS2O3) from lime, sulfur and oxygen is described. By selecting appropriate process conditions such as mole ratios of lime to sulfur, temperature and pressure of the reaction process and the oxidation conditions, including rate and duration, the concentration of byproducts in the resulting suspension can be reduced to about 2% by weight or less. The solid particulate dispersion in the suspension tends to form a slimy solid suspension that is hard to filter if not treated properly. The suspension then can be acidified and treated with a flocculent. This agglomerates the solids into a floc that filters with ease. The resulting calcium thiosulfate is a clear liquid with concentrations achievable up to 29%.

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H. Ballezo and O. Kaufmann,Calciumthiosulfat, 12 pages, Oct., 1948.
English Abstract for RU 2 167 101 C2 (Gipronikel Inst. Stock Co), May 20, 2001, “Method of Preparing Thiosulfates”.

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