Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium
Reexamination Certificate
1997-06-30
2001-05-29
Griffin, Steven P. (Department: 1754)
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Group iiia metal or beryllium
C423S155000, C423S600000, C501S153000, C501S154000, C501S155000, C106S692000, C106S693000, C106S753000, C075S303000, C075S416000, C075S568000, C075S570000
Reexamination Certificate
active
06238633
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to aluminum dross and more particularly, it relates to the use of oxide products or non-metallic products (NMP) recovered from aluminum dross.
Aluminum dross results from the melting of aluminum scrap such as used beverage containers, aluminum siding, castings and the like and treating the melt with salt flux. The salt flux accumulates on top of the melt and forms a dross or skim which contains aluminum, oxides of aluminum and elements such as magnesium and silicon and other alloying elements present in the various alloys. Further, the skim contains other non-metallic products or compounds of the aluminum and alloying elements. The dross is removed or skimmed from the melt and processed usually to recover the metallic aluminum occluded in the oxides and non-metallic compounds. The aluminum can constitute 5 to 70% of the dross. Usually, the aluminum, which is considered the most valuable component, is recovered from the solidified dross by first fracturing the dross, for example, by mechanical milling and screening out the aluminum. Thereafter, fractured dross is heated in the presence of additional salt flux to free metallic aluminum. The molten salt flux aids in releasing molten aluminum from the dross. The salt flux is usually comprised of sodium chloride and potassium chloride. After a major portion of metallic aluminum is removed, the dross is comprised of three major components which are aluminum, salt flux and an insoluble constituent comprised largely of aluminum oxide, silicon oxide and magnesium oxide, and other non-metallic compounds often referred to as salt cake. The three components can be present in the ranges of about 3 to 25 wt. % aluminum, 25 to 50 wt. % salt flux and 25 to 75 wt. % NMP. The NMP is comprised mainly of compounds such as oxides of aluminum, silicon and magnesium. Also, included in the salt cake are minor amounts of oxides and other compounds of titanium, copper, zinc, sulfur, potassium and sodium which constitute part of the NMP. The titanium, copper and zinc compounds, e.g., oxides, can be present from alloying elements in the aluminum scrap. It is desirable to recover all useful constituents from the salt cake. Thus, the salt cake is treated to recover the salts, the insoluble constituents or non-metallic product and any remaining aluminum metal. In particular, for purposes of the present invention, it is highly desirable to recover an NMP substantially free of aluminum metal or aluminum nitride.
The salt cake can be advantageously treated in accordance with the procedures set forth in U.S. Pat. Nos. 5,102,453 and 5,227,143. However, even after such treatment, there remains the insoluble constituent or non-metallic product. U.S. Pat. No. 5,102,453 discloses the problems attendant the presence of magnesium from magnesium-containing alloys and the problems resulting from the addition of magnesium chloride to the recovery system. Namely, such addition increases the overall amount of magnesium chloride contained in the unrecoverable material or non-metallic product and even when disposed of in plastic film-lined landfills, problems still result. Thus, often the process of leaching the salt cake is not optimized to avoid disposal problems with non-metallic product.
Thus, it will be seen that there is a great need for a process that enables the recovery of the non-metallic product thereby recovering all the constituents from the aluminum dross and avoiding any dumping of NMP in landfills. The present invention provides such a process.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an improved process for treating salt cake.
It is another object of the invention to provide an improved process for recovering salts and non-metallic product from salt cake.
Yet, it is another object of the present invention to recover both the salts and the NMP from salt cake.
And yet, it is another object of the present invention to provide a process for treating salt cake to recover all the components therein and provide an NMP substantially free of aluminum metal and aluminum nitride and form aluminate from the NMP.
In accordance with these objects there is provided a process for preparing a calcium aluminate product from a salt-containing aluminum dross containing aluminum metal, water-insoluble material and fluxing compounds. The process comprises crushing the salt-containing aluminum dross and separating the aluminum metal therefrom. The crushed dross is treated in a digester with water to dissolve water-soluble compounds contained therein to provide an aqueous solution containing both soluble and insoluble materials. The aqueous solution containing soluble materials is separated from the insoluble material to provide a separate solution. Thereafter, the separated solution may be evaporated to crystallize fluxing compounds and to provide an evaporator liquor containing magnesium chloride. A part of the evaporator liquor may be recycled back to the digester in an amount sufficient for the magnesium chloride contained therein to control the pH of the materials in the digester. A body of NMP is recovered from the insoluble material. A major portion of the NMP is comprised of aluminum compounds, e.g., Al
2
O
3
, and a minor portion is comprised of compounds of silicon and magnesium, for example, oxides of silicon and magnesium. The NMP recovered is substantially free of aluminum metal and aluminum nitride. A source of calcium oxide is added to the NMP to provide a blend, the blend is formed into discrete bodies which are heated to a temperature in the range of about 2000° F. (1093° C.) to 2300° F. (1260° C.) to form the calcium aluminate product.
REFERENCES:
patent: 4033782 (1977-07-01), Ray et al.
patent: 4395282 (1983-07-01), Braun et al.
patent: 4490173 (1984-12-01), Schwer
patent: 5102453 (1992-04-01), Yerushalmi
patent: 5132246 (1992-07-01), Brisson et al.
patent: 5135565 (1992-08-01), Gens
patent: 5203908 (1993-04-01), Lindsay
patent: 5227143 (1993-07-01), Stewart, Jr. et al.
patent: 5308375 (1994-05-01), Lindsay
patent: 5385601 (1995-01-01), Kemeny et al.
patent: 5407459 (1995-04-01), Breault et al.
patent: 5424260 (1995-06-01), Yerushalmi et al.
patent: 5447548 (1995-09-01), Lindsay
patent: 5540752 (1996-07-01), Spoel
patent: 5603759 (1997-02-01), Burkhart
patent: 5613996 (1997-03-01), Lindsay
patent: 0733591 (1996-09-01), None
patent: 0753491 (1997-01-01), None
patent: 8290951 (1996-11-01), None
patent: 9508516 (1995-03-01), None
Light Metals 1995, Proceedings of the technical sessions presented by the TMS Light Metals Committee at the 124th TMS Annual Meeting, Las Vegas, Feb. 12-16, 1995, pp. 823-827.
Castelijns, C.A.M. et al, The Re-Use of Non-Metallic Products Obtained from Salt Free Aluminum Dross Recycling.
Morris Edward L.
Pickens John W.
Alexander Andrew
Aluminum Waste Technology, Inc.
Griffin Steven P.
Nguyen Cam N.
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