Process for preparing bisimide products

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D20948

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active

049925571

ABSTRACT:
In a first embodiment this invention relates to a process for preparing a white product which principally contains a bisimide. The process comprises: providing tetrabromophthalic anhydride and a solvent in a reaction vessel; forming, at a temperature within the range of from about 140.degree. C. to about 200.degree. C., a reaction mass by adding a diamine, a diamine salt or a mixture thereof to the solution, the formation of the reaction mass resulting in the production of a bisimide precipitate which becomes a component of the reaction mass; terminating the addition of the diamine when the molar ratio of the tetrabromophthalic anhydride initially present in the solution to the diamine or diamine salt added is substantially stoichiometric; cooking the bisimide precipitate to increase the average sphericity of the particles making up the bisimide precipitate; and recovering from the reaction mass, as the bisimide product, the cooked precipitate. In a second embodiment the cooking step is optional and the retention of water formed during the diamine or diamine salt addition is featured.

REFERENCES:
patent: 3868388 (1975-02-01), Dotson
patent: 3966726 (1976-06-01), Toth
patent: 4092345 (1978-05-01), Wolford
patent: 4125535 (1978-11-01), Wolford
patent: 4374220 (1983-02-01), Sonnenberg
patent: 4535170 (1985-08-01), Sonnenberg
patent: 4581396 (1986-04-01), Sonnenberg

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