Process for preparing bead polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 71, 526206, 526207, 526219, 526287, 526292, 526909, 526910, 526923, C08F 208, C08F 220, C08F12000, C08F22200

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041587260

ABSTRACT:
Disclosed is a process for preparing a water-soluble bead polymer by dispersing drops of an aqueous solution of water-soluble vinyl monomer in a dispersing medium in the presence of a dispersion stabilizer, and polymerizing the monomer by using monomer selected from the following A and B
(a) a compound of the general formula I ##STR1## wherein R.sup.1 is hydrogen or methyl, R.sup.2 and R.sup.3 may be the same or different and each is linear or branched alkyl of from 1 to 4 carbon atoms, R.sup.4 is hydrogen, linear or branched alkyl of from 1 to 8 carbon atoms, hydroxy alkyl of from 1 to 4 carbon atoms, or benzyl, Y is alkylene or hydroxyalkylene each of from 2 to 4 carbon atoms, and X.sup.- is an anion, or
(B) a mixture of the compound of the formula I and a water-soluble vinyl monomer copolymerizable with the compound (I), and a cellulose ester or a cellulose ether insoluble in water but soluble in the dispersing medium is used as the dispersion stabilizer.

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patent: 4060678 (1977-11-01), Steckler

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